Evaluación de la Isomerización de Epóxido de α-Pineno a Aldehído Canfolénico Utilizando un Catalizador Obtenido de Cáscaras de Naranja (Citrus sinensis)

• Aída Luz Villa Grupo de Investigación de catálisis ambiental, Departamento de Ingeniería Química, Universidad de Antioquia, Medellín, Antioquia, Colombia https://orcid.org/0000-0002-3770-3223
• Marta Mediavilla Facultad de Ingeniería, Universidad Central de Venezuela, UCV, P.O. Box 48.057, Caracas 1041-A, Venezuela https://orcid.org/0000-0001-9010-9795

DOI: https://doi.org/10.22209/rt.v46a03

Palabras clave: carbón, DRX, mesoporos, residuo, terpenos

Resumen

Las cáscaras de naranja (Citrus sinensis) son residuos lignocelulósicos abundantes que pueden ser utilizados como fuente de carbono para obtener sólidos con potencial catalítico en la transformación de terpenos y sus óxidos en productos de valor agregado. Esta investigación buscó evaluar la isomerización de óxido de α-pineno a aldehído canfolénico, utilizando un catalizador obtenido de cáscaras de naranja. El material OAC-Zn se obtuvo por activación de las cáscaras con ZnSO₄.7H₂O, seguido de tratamiento térmico a 500 °C; también se obtuvo un sólido de la pirólisis de la cáscara a 500 °C (OC-500). Mediante DRX se identificó la presencia de ZnO y ZnS en OAC-Zn; los análisis por TGA indicaron estabilidad térmica en OAC-Zn y OC-500; las imágenes SEM mostraron superficies porosas de diferente morfología, así como la presencia de microporosidad en OC-500 y de mesoporosidad en OAC-Zn, que fueron confirmadas mediante adsorción física de nitrógeno. En los análisis EDX se identificaron los elementos C, O, Zn y S en OAC-Zn; los resultados de TPD-NH₃ mostraron que los sólidos contenían acidez media y débil. Se sintetizó aldehído canfolénico con selectividad de 96 % sobre un material carbonoso mesoporoso, a partir de cáscaras de naranja utilizando ZnSO₄.7H₂O como agente activador

Citas

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